Diisopropyl(6-(phenyl(phenylthio)arsaneyl)-1,2-dihydroacenaphthylen-5-yl)phosphane

Molbank 2026 Open access

Read full text
Authors: Laurence J. Taylor, Philip M. Pickett, David B. Cordes, Petr Kilián
DOI: 10.3390/m2139
Cited by: 0
References: 7

Abstract

Peri-substituted bis(tertiary) phosphine-arsine Acenap(PiPr2)(As(SPh)Ph) (4, Acenap = acenaphthene-5,6-diyl) was synthesized by the reaction of the chloroarsine (PiPr2)(AsPhCl) with PhSLi. The X-ray crystal structure of this compound reveals an intramolecular P∙∙∙As–Cl pnictogen bond, with the phosphorus lone pair donating into the As–S σ* orbital.

Fields of Study & Subjects

Synthesis and characterization of novel inorganic/organometallic compounds Organophosphorus compounds synthesis Phosphorus compounds and reactions

Publication details

Journal / source
Molbank
Volume
2026
Issue
1
Pages
M2139–M2139
Publication date
10 February 2026
Language
EN