MOF-Derived Carbon-Anchored Cu2Se/MnSe Heterointerfacial Nanoparticles for Enhanced Lithium Storage via Synergistic Interface Effects

To address the inherent limitations of Cu2Se as a lithium-ion battery (LIB) anode, a Cu2Se/MnSe@C composite was rationally designed and synthesized via selenization of a CuMn bimetallic metal–organic framework (MOF) precursor. This synthesis strategy integrates carbon composite engineering and heterogeneous structure construction, achieving in situ formation of Cu2Se/MnSe heterogeneous nanoparticles anchored on amorphous carbon nanosheets. Structural characterizations confirm the successful construction of well-defined Cu2Se/MnSe interfaces and uniform dispersion of selenide components, with Mn introduction inducing regulated electron transfer between Cu2Se and MnSe. Electrochemical evaluations demonstrate that the Cu2Se/MnSe@C composite exhibits a significantly enhanced lithium storage performance compared to single-component Cu2Se@C, including higher specific capacity and superior rate capability. Mechanistic studies reveal that the synergistic effects of the carbon matrix (enhancing electrical conductivity and mitigating volume expansion) and the Cu2Se/MnSe heterogeneous interface (lowering charge transfer resistance, accelerating Li+ diffusion, and boosting pseudocapacitive contribution) are responsible for the performance enhancement. Moreover, Cu2Se/MnSe@C||LiFePO4 full cells deliver a stable average operating voltage and reliable cycling stability, validating the composite’s practical application potential.