Synthesis of a Mixed Bis(imino)acenaphthene (BIAN) Ligand Using Aluminum Transfer Reagents

Molecules 2026 Open access

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Authors: Kalyan V. Vasudevan, Nicholas J. Hill, Daniel K. Unruh, Andrew K. King, Alan H. Cowley, Michael Findlater
DOI: 10.3390/molecules31122185
Cited by: 0
References: 28

Abstract

Aminoalane and iminoalane transfer reagents are employed in the synthesis of ketoimines based upon an acenaphthene scaffold. One of the ketoimine species is subsequently used as a precursor for the synthesis of a mixed-BIAN ligand which features both perfluorophenyl- and tert-butyl substituents.

Fields of Study & Subjects

Asymmetric Synthesis and Catalysis Synthetic Organic Chemistry Methods Chemical Synthesis and Analysis

Publication details

Journal / source
Molecules
Volume
31
Issue
12
Pages
2185–2185
Publication date
22 June 2026
Language
EN