Comprehensive Analysis of Temperature-Dependent Photoluminescence in Silica-Encapsulated CsPbBr3 and CsPbI3 Perovskite Nanocrystals
Abstract
The temperature-dependent photoluminescence of CsPbBr3/SiO2 and CsPbI3/SiO2 nanocrystals was investigated to understand the thermal stability of SiO2 encapsulation. At increased temperature, intensity quenching, linewidth broadening, energy level shift, and decay dynamics were evaluated as quantified parameters. Comprehensive analysis of these parameters supports that CsPbI3/SiO2 nanocrystals show a stronger interaction with phonons compared with CsPbBr3/SiO2 nanocrystals. Despite SiO2 encapsulation, we conclude that trapping states are still present and the degree of localization can be characterized in terms of short-lived decay time and thermal activation energy.
Fields of Study & Subjects
Perovskite Materials and Applications
Luminescence Properties of Advanced Materials
Optical properties and cooling technologies in crystalline materials
Publication details
- Journal / source
- Nanomaterials
- Publisher
- MDPI AG
- Volume
- 16
- Issue
- 1
- Pages
- 76–76
- Publication date
- 5 January 2026
- Language
- EN