Simulation Study of Influence of Nano-Confinement Effect on Shale Fluid Phase Characteristics: A Case Study of Gulong Shale Oil

Songliao Basin hosts abundant shale oil and gas resources, yet the phase behavior of the fluids is still unclear since the confinement effect of the shale reservoir alters the adsorption effect on the pore walls. In this study, molecular dynamics (MD) simulations were employed to clarify this issue. A binary mixture was built to represent Gulong shale oil and the phase state properties under the confinement effect were evaluated. In addition, a series of pure alkane models were constructed to analyze the influence of hydrocarbon type, temperature, and mineral composition on phase behavior. The simulation results showed that the typical Gulong shale fluid remains liquid state in the nanopores. Owing to the confinement effect, both viscosity and density under nano space decrease sharply compared to those at bulk space. Therefore, field development should somewhat rely on high-pressure stimulation to create flow paths, followed by CO2 huff-and-puff technology to maintain production pressure. In addition, fluid composition, temperature, and mineral type are the primary factors governing the magnitude of the confinement effect.