Chlorophyll Retrieval in Sun Glint Region Based on VIIRS Rayleigh-Corrected Reflectance

Sun glint is commonly observed as interference in the imaging process of ocean color satellite sensors, making the extraction of water color information in sun glint-affected areas challenging and often leading to significant data gaps. The remote sensing baseline indices, calculated based on Rayleigh-corrected reflectance (Rrc), are recognized as effective in reflecting water color variability in sun glint-affected regions. However, the accurate extraction of the Rrc baseline indices requires sun glint correction. The determination of sun glint correction coefficients for different bands lacks a clear methodology, and the currently available correction coefficients are not applicable to different sea regions. Therefore, this study focuses on the South China Sea, where VIIRS imagery is significantly affected by sun glint. Based on paired datasets comprising sun glint-affected and -unaffected images acquired over the same region on adjacent dates, sun glint correction coefficients for each spectral band were derived by maximizing the cosine similarity of histograms constructed from three baseline indices: SS486 (Spectral Shape index at 486 nm), CI551 (Color Index at 551 nm), and SS671 (Spectral Shape index at 671 nm). To further evaluate the effectiveness of the proposed correction, chlorophyll-a concentrations were retrieved using a Random Forest regression model trained with baseline indices derived from sun glint-free Rrc data and subsequently applied to baseline indices after sun glint correction. Comparative analyses of both baseline index extraction and chlorophyll-a retrieval demonstrate that the proposed optimal-value and mean-value correction approaches effectively mitigate sun glint effects. The mean sun glint correction coefficients α(443), α(486), α(551), α(671) and α(745) were determined to be 0.75, 0.83, 0.89, 0.95 and 0.94, respectively. These coefficients can be applied as sun glint correction coefficients for the VIIRS Rrc data in the South China Sea region. Furthermore, the proposed method for determining sun glint correction coefficients offers a transferable framework that can be extended to other sea areas.