Hyperspectral Unmixing-Based Remote Sensing Inversion of Multiple Heavy Metals in Mining Soils: A Case Study of the Lengshuijiang Antimony Mine, Hunan Province

Soil heavy metal contamination in mining areas poses a serious environmental challenge, requiring monitoring approaches with both wide coverage and high accuracy. Hyperspectral remote sensing provides an effective solution, yet its performance in complex mining environments is often limited by mixed-pixel effects and nonlinear spectral responses. To address these issues, this study proposes a Physically-Constrained Collaborative Endmember Extraction (PCCEE) framework that integrates spectral unmixing with machine learning for multi-element inversion. Using Gaofen-5 hyperspectral imagery, a collaborative workflow combining Pixel Purity Index (PPI), Vertex Component Analysis (VCA), and prior-spectral-constrained Spectral Angle Mapper (SAM) was developed to improve endmember purity and physical interpretability. Among three unmixing models (LMM, NMF, and SVR), the Linear Mixing Model achieved the best balance between accuracy and efficiency. Random Forest regression using retrieved abundances enabled high-accuracy inversion of eight heavy metals (mean R2 = 0.85). Spatial analysis revealed significant co-enrichment of Pb, Cd, and Zn related to sulfide weathering, while PCA distinguished compound and independent pollution sources. The proposed PCCEE framework effectively mitigates mixed-pixel interference and provides a transferable approach for heavy metal monitoring and risk assessment in complex mining environments.