High-Performance Self-Powered Photodetector Based on Silver Triangular Nanoplate-Modified P3HT/ZnO Heterojunctions

Self-powered photodetectors have attracted widespread attention in Internet of Things applications due to their low power consumption and high sensitivity. In this study, plasmonic self-powered poly(3-hexylthiophene)/zinc oxide (P3HT/ZnO) heterojunction photodetectors incorporating silver triangular nanoplates (AgTNPs) were fabricated using sol-gel and spin-coating techniques. The experimental results demonstrate that the incorporation of AgTNP nanostructures significantly enhances the photoelectric conversion efficiency of the plasmonic P3HT/AgTNPs/ZnO photodetectors across both the ultraviolet and visible spectral regions. The responsivity enhancement ratio of the plasmonic devices reached its maximum under illumination at a wavelength of 525 nm. Compared with the reference P3HT/ZnO device, the responsivity values of the P3HT/AgTNPs-1/ZnO and P3HT/AgTNPs-2/ZnO devices increased by factors of 3.24 and 4.21, respectively. The optimal P3HT/AgTNPs-2/ZnO device exhibited responsivity values of 9.49, 10.80, and 10.47 mA/W under irradiation at wavelengths of 440 nm, 460 nm, and 525 nm, respectively. The mechanism of performance enhancement induced by the plasmonic AgTNPs is also discussed. This work demonstrates that embedding triangular plasmonic metal nanoplates within semiconductor heterojunctions constitutes an effective strategy for performance enhancement, providing new insights for the rational design of high-performance optoelectronic devices.