Programmable Interface Atomic Rearrangement for Spatiotemporal Thermal Radiation Tailoring

The modulation of thermal radiation is essential for advanced photonic applications, offering a novel perspective for information carriers. However, current carriers are limited to a few discrete radiation states at isolated time points and cannot capture the entire dynamic process along the full temporal axis, resulting in substantial information loss. Here, we propose and experimentally validate a novel spatiotemporal modulation strategy that dynamically tailors emissivity across the entire temporal domain, where gentle and uniform modulation of atomic configurations enables the creation of entirely novel permittivity libraries. To realize flexible thermal radiation tailoring, we utilize an Ag–In 3 SbTe 2 (IST) interface atomic rearrangement metamaterial (ARM). As a dynamic optical control platform, ARM exhibits continuous spectral modulation with remarkably high amplitudes (64.74% in the 3- to 5-μm band and 73.94% in the 8- to 14-μm band), together with rich variations across the temporal domain to realize tailored infrared emissivity and infrared information encryption. This work establishes a unified framework for continuous, atomic-scale spatiotemporal control of thermal radiation, opening new pathways for spectral modulation and photonic information regulation in the time domain.