C, N, O, S, and Photochemistry in a Temperate Giant Planet Orbiting a Late M Dwarf

Abstract We report the JWST NIRSpec/PRISM transit spectrum of TOI-6894 b, an exceptional 420 K sub-Saturn that is one of the rare giant planets transiting a late M dwarf. Remarkably, both the light curve and the transit spectrum exhibit almost no stellar contamination. The spectrum is dominated by prominent absorption features from CH 4 and the photochemical product CS 2 . For the first time in a transit spectrum, NH 3 is visually evident, while subtler features from H 2 O and CO 2 can also be seen. We significantly improve upon state-of-the-art photochemical reaction networks, and use our new network to run radiative-convective photochemical (“RCP”) models at different metallicities. These models show that the spectrum—in particular the size of the NH 3 and CO 2 features relative to the CH 4 and H 2 O features—is most consistent with a metallicity of 3–10× solar. Using a semi-free retrieval framework that perturbs the RCP model’s abundance and temperature profiles to fit the data, we find that the planet’s C/O, N/O, and S/O ratios are consistent with solar values. A grid retrieval on 1D RCP equilibrium models reveals a similar result: [M/H] = 0.46 ± 0.08 and C/O = 0.69 ± 0.06. The planet’s atmospheric metallicity, abundance ratios, and bulk metal fraction are all strikingly similar to those of Jupiter, Saturn, and other gas giant exoplanets, despite orbiting a very low-mass star.