Active Phase-Support Interaction in Phosphotungstic Acid-SiO₂ Catalysts Enables Enhanced Olefin Oligomerization to Synthetic Fuel

Transitioning the aviation sector to synthetic aviation fuels (SAF) requires innovative catalytic processes to overcome common limitations such as insufficient activity, selectivity, and catalyst deactivation. This study presents a detailed exploration of silica-supported phosphotungstic acid (PTA/SiO2) as a robust solid acid catalyst for propylene conversion into jet fuel-range hydrocarbons (C8 to C16) at mild reaction conditions (150 °C). The catalyst with optimized PTA loading (10 wt %) demonstrates significant oligomerization performance, achieving high selectivity to jet fuel-range hydrocarbons (>80%) and propylene conversion (>90%), alongside limited aromatic byproducts formation. Compared to conventional solid-acid catalysts such as a ZSM-5 zeolite, PTA/SiO2 exhibits significantly reduced catalyst deactivation and can be regenerated through mild thermal treatment (