Bioplastic Films Derived from Corn Cob Waste and ZnO from Battery Waste: Mechanical Properties and Electrical Conductivity

Bioplastics or biopolymers are being developed as an alternative to tackle the problem of polymer waste, which causes pollution and greenhouse gas emissions. Cellulose derived from corn cobs can be a biopolymer alternative to synthetic polymers. Cellulose derived from corn cobs can replace conventional petroleum-based polymers as an alternative plastic material. Incorporating ZnO into the biopolymer matrix is projected to result in favourable characteristics and allow for a wider range of applications. This study aims to investigate the changes in the characteristics of bioplastics derived from corn cob waste and starch upon the incorporation of ZnO, with a special emphasis on mechanical properties and electrical conductivity. FTIR analysis shows that the incorporation of ZnO exhibited no impact on the structure of the bioplastic. Scanning electron microscopy (SEM) analysis revealed that the ZnO microparticles' morphology is irregular and rough. The average size of ZnO particles incorporated into the biopolymer matrix was 0.623 μm. Mechanical tests showed a positive correlation between the amount of ZnO and the tensile strength of bioplastics. The assessment of the electrical conductivity of the Bioplastic/ZnO composite indicates a notable enhancement with the inclusion of ZnO. Electrical conductivity shows a progressive increase from 2.13x10 -15 S/m to 3.23x10 -12 S/m, 7.42x10 -11 S/m, and 2.03x10 -10 S/m with the incorporation of ZnO as much as 0.03, 0.06, and 0.09 g, respectively. Generally, incorporating ZnO into bioplastics can enhance their tensile strength and electrical conductivity.