Influence of Filler on the Interfacial Strength between TPE and PP Composites

The influence of filler type and content on the wettability and interfacial bonding between thermoplastic elastomer (TPE) and polypropylene (PP) by using the injection overmolding process was investigated in this study. Calcium carbonate (CaCO 3 ) and talcum (Talc) masterbatchs, ranging from 0 to 40 percent by weight (wt%), were mixed into the PP matrix as fillers. The bond strength of TPE overmolded onto PP composites was characterized by the tensile and tear tests. Good compatibility was observed between TPE and PP filled with various amounts of CaCO 3 and Talc. In the case of the tensile test, the crack initiation stress, ultimate tensile strength, strain at break, and bond energy were found to decrease with increasing filler content. The results obtained from the tear test indicated that the propagation strength, ultimate tear strength, strain at break, and bond energy of injection overmolded TPE-PP filled with various CaCO 3 contents did not significantly change compared to those obtained from Talc. This can be attributed to the high reinforcing efficiency of Talc in comparison with CaCO 3 , which can enhance the stiffness and thermal resistance of the PP matrix. As a result, the contact area becomes more resistant to molecular diffusion of TPE chains, particularly at high Talc loadings (30 and 40 wt%), leading to the reduction of interfacial bonding.