A Thin-Film Flexible Temperature-Strain Multimodal Sensor for Lithium-Ion Battery Monitoring Based of Laser Direct Writing

Multimodal sensors, capable of simultaneously acquiring multiple physical or chemical signals, have shown broad application potential in fields such as health monitoring, soft robotics, and energy systems. However, current multimodal sensors often suffer from complex fabrication processes and signal decoupling challenges, which limit their practical deployment. To address these issues, this work presents a thin-film temperature–strain multimodal sensor (FTSMS) fabricated via laser processing. The temperature-sensing unit, based on the Seebeck effect, achieves a sensitivity of 9.08 μV/°C, while the strain-sensing unit, utilizing BaTiO₃/AlN@PDMS as the sensitive layer, exhibits a gauge factor (GF) of 43.2. By integrating distinct sensing mechanisms (thermovoltage for temperature and capacitance change for strain), the FTSMS enables self-decoupled measurements over 20–90 °C. Applied in LIB monitoring, it successfully captures real-time temperature and strain variations during charge-discharge cycles and provides multidimensional information throughout thermal runaway (TR) processes, enabling early TR warning and supporting safety-oriented battery design.