Emission-line Diagnostics at $z\gtrsim 2$: A Probe of the Ionizing Spectrum and $α$ Enhancement Beyond Cosmic Noon

We analyze several key rest-optical emission-line ratios in a sample of 828 galaxies as well as composite spectra from JADES DR3 in the range $1.4 < z < 7$. These emission-line ratios include: [O III]$\lambda5008$/H$β$, [N II]$λ6585$/H$α$, [S II]$λλ6718,6733$/H$α$, [O I]$λ6302$/H$α$, O32, R23, Ne3O2, and RO2Ne3. We find evidence for a harder ionizing spectrum at $z\sim 3.5$ compared to $z\sim 2$ at fixed gas-phase metallicity, resulting in a pronounced shift in the star-forming galaxy locus on the [N II]/H$α$ BPT diagram and the O32 vs. R23 diagram. At $z\gtrsim 3.5$, star-forming galaxies occupy a common locus, indicating that ISM ionizing conditions at fixed gas-phase metallicity do not evolve strongly at these early cosmic times. There is a connection between ISM ionizing conditions and the chemical abundance patterns (i.e., $α$/Fe) in massive stars providing the ionizing radiation field. Therefore, the lack of evolution in ISM ionizing conditions at $z\gtrsim 3.5$, followed by evolution towards a softer ionizing spectrum at fixed nebular metallicity as cosmic time proceeds to $z\sim 2$ and lower redshift mirrors the chemical abundance patterns in Milky Way stars as a function of iron abundance. Our results highlight the diagnostic power of emission-line diagrams in the era of JWST to further our understanding of the ISM conditions into the Epoch of Reionization.