Is gelation a singularity or a flow induced instability?
Abstract
Gelation in the Smoluchowski coagulation equation is commonly interpreted as a finite-time singularity marked by mass loss or moment divergence. We instead characterize gelation as a loss of dynamical stability of the Smoluchowski flow, quantified through the time-dependent spectrum of the Jacobian along the evolving aggregation dynamics. Studying homogeneous kernels $K(i,j)=(ij)^α$ together with the classical Smoluchowski, we show that gelation is consistently preceded by the appearance of positive real eigenvalues, indicating a loss of local dynamical stability. While non-gelling kernels exhibit only transient finite-size effects, gelling kernels display persistent spectral destabilization associated with macroscopic gel formation. Our results identify gelation as a genuine dynamical instability of the Smoluchowski flow.
Fields of Study & Subjects
Stochastic processes and statistical mechanics
Statistical Mechanics and Entropy
Theoretical and Computational Physics
Publication details
- Journal / source
- arXiv (Cornell University)
- Publication date
- 15 January 2026
- Document type
- Preprint