Classical Resolution of the Gibbs Paradox from the Equal Probability Principle: An Informational Perspective

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Authors: Zheng Zhang
Cited by: 0

Abstract

The Gibbs paradox is a conventional paradox in classical statistical mechanics, typically resolved by invoking quantum indistinguishability through the 1/N! correction. In this letter, we present a resolution within classical ensemble theory, which relies solely on the equal probability principle and does not invoke the 1/N! correction. Our resolution can be naturally interpretated from a purely informational perspective, where the Gibbs entropy is explicitly regarded as the Shannon entropy, quantifying ignorance rather than disorder. From this informational perspective, we also clarify the connection between information and extractable work in the gas mixing processes. Our work opens a new avenue to reconsider the role of information in statistical mechanics.

Fields of Study & Subjects

Advanced Thermodynamics and Statistical Mechanics Statistical Mechanics and Entropy Quantum Mechanics and Applications

Publication details

Journal / source
arXiv (Cornell University)
Publication date
6 February 2026
Document type
Preprint