Dual role of core electrons in electronic friction

Non-equilibrium energy dissipation in multi-shell swift-ion/matter systems remains a fundamental yet incompletely understood problem, with electronic stopping power \(\mathcal{S}_\text{e}\) as a relevant observable for electronic friction. Using real-time time-dependent density functional theory, we perform first-principles calculations of \(\mathcal{S}_\text{e}\) for beryllium self-irradiation with explicit treatment of all electrons. Our results reveal a Bragg peak exhibiting a distinct structure which lies beyond the reach of standard models. We attribute its appearance to a dual effect of the presence of core electrons, by which their excitation provides an additional dissipation channel while simultaneously suppressing valence electron excitations, contrary to earlier proposals. Electron capture by the projectile's core from the host cores is behind such suppression rather than Pauli blocking.