A proposed route to metastable room-temperature superconductivity in Li₂MgB₂H₁₈

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Authors: Travaglini, Giustino
Cited by: 0

Abstract

The realization of room-temperature superconductivity at ambient pressure remains the ultimate goal of condensed matter physics. While high-pressure superhydrides (e.g., 𝐿𝑎𝐻10) have achieved high critical temperatures (Tc), they lose stability upon decompression. Here, I predict a novel ternary clathrate structure, 𝐿𝑖2 𝑀𝑔 𝐵2𝐻18, designed to maintain high-Tc superconductivity at 0GPa via a "kinetic locking" mechanism. First-principles calculations reveal that a rigid Boron-Magnesium host lattice can chemically confine dense hydrogen clusters, mimicking the effects of external pressure. I estimate a Tc of ~298 K driven by strong electron-phonon coupling (𝜆≈2.6). Furthermore, I propose a cryogenic decompression protocol ("Cryo-Lock") to synthesize and stabilize this metastable phase for ambient-pressure operation

Fields of Study & Subjects

High-pressure geophysics and materials Superconductivity in MgB2 and Alloys Boron and Carbon Nanomaterials Research

Publication details

Journal / source
Zenodo (CERN European Organization for Nuclear Research)
Publication date
5 September 2026
Language
EN