ARCHITEKTURY KOORDYNACYJNE, SUPRAMOLEKULARNE ORAZ TYPU GOŚĆ-GOSPODARZ: OD INŻYNIERII STRUKTURALNEJ PO APLIKACJE BIOLOGICZNE, MEDYCZNE I KATALITYCZNE

The paper reviews new functional silver(I) coordination networks and materials with strong antibacterial, antiviral, antifungal, and cytotoxic effects against cancer cells. It also discusses the anticancer potential of ruthenium(II) and copper(I/II) heteroleptic complexes with various ligands and counterions. Promising in vivo results in photodynamic therapy (PDT) using glycosylated zinc phthalocyanines suggest their potential in treating psoriasis. Additionally, the study highlights copper(I) complexes as efficient catalysts in click chemistry (CuAAC) and copper(II) carboxylates as active catecholase enzyme models using 3,5-DTBC as a substrate. Additionally, a series of coordination compounds was synthesized via the reaction of copper(I) or silver(I) salts with 1,2,4-triazolo-4-amine derivatives, resulting in both porous and stimuli-responsive (breathing) crystals, which are also characterized and discussed in this work. Keywords: