Higher-order Derivative Voltabsorptmetry of Tris(acetylacetonato)iron (III) Complex in Acetonitrile

Electrochemistry 2026 Open access

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Authors: Shinya KISHIOKA
DOI: 10.5796/electrochemistry.25-00174
Cited by: 0
References: 39

Abstract

A voltaborptmetric property of tris(acetylacetonato)iron (III) (Fe(acac)3) in acetonitrile in an optically transparent thin layer cell was investigated.The obtained electronic absorption spectra were analyzed using the higher-order derivative conversion (HODC) up to the eighth order.The Nernst equation can analyze the potential dependence of the sub-peak obtained by the HODC, and the HODC method is shown to be effective for studying the spectroelectrochemistry of metal complexes dissolved in non-aqueous systems.

Fields of Study & Subjects

Electrochemical Analysis and Applications Photochemistry and Electron Transfer Studies Inorganic and Organometallic Chemistry

Publication details

Journal / source
Electrochemistry
Volume
94
Issue
2
Pages
027011–027011
Publication date
15 January 2026
Language
EN