Pd@CN-COF: a pool for palladium(0)-catalyzed reactions

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Authors: Marcela Horáková, Milan Klikar, Jakub Halamek, Roman Bulánek, Jhonatan Rodríguez‐Pereira, Veronika Čičmancová, Jan Podlesný, Eva Kolíbalová, Jan Michalička, Jan Bartáček, Patrik Pařík, Jan M. Macák
+1 more Filip Bureš
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Abstract

New cyanovinylene-linked COF (CN-COF) was designed, synthesized, and utilized as a support for palladium nanoparticles. The resulting Pd@CN-COF was fully characterized, and its catalytic performance was evaluated in seven palladium-catalyzed reactions, including cross-coupling reactions, cyanation, and allylic substitution. The catalytic activity of Pd@CN-COF was further demonstrated in synthetically valuable transformations leading to industrially, agrochemically, and pharmacologically relevant products.

Fields of Study & Subjects

Covalent Organic Framework Applications Catalytic Cross-Coupling Reactions Catalytic C–H Functionalization Methods

Publication details

Journal / source
Figshare
Publication date
5 March 2026
Language
EN
Document type
Dataset