Chiral acyclic diaminocarbene complexes of palladium(II), platinum(II) and gold(I) from metal-mediated coupling of isocyanides with chiral amino acid amides

Mendeleev Communications 2026

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Authors: Tatyana B. Anisimova, Maria V. Kashina, Mikhail A. Kinzhalov, M. Fátima С. Guedes da Silva, Armando J. L. Pombeiro, Konstantin V. Luzyanin
DOI: 10.71267/mencom.7888
Cited by: 0
References: 30

Abstract

The reaction between enantiopure amino acid amides and metal-coordinated isocyanides such as cis-[Cl2M(CNR)2] (M = Pd, Pt) and [ClAu(CNR)] affords chiral acyclic diaminocarbene complexes in 64 to 91

Fields of Study & Subjects

Organometallic Complex Synthesis and Catalysis N-Heterocyclic Carbenes in Organic and Inorganic Chemistry Cyclopropane Reaction Mechanisms

Publication details

Journal / source
Mendeleev Communications
Volume
36
Issue
2
Pages
135–137
Publication date
1 January 2026
Language
RU