New gold(I) complexes with fluorinated tricyclic NHC ligands: synthesis and catalytic activity

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Authors: Pavel Sergeevich Gribanov, Anna Nikolaevna Philippova, D. Vorobyeva, Timur Rikzaevich Akmalov, Salekh Masoud Masoud, Alexander Fedorovich Smol'yakov, Sergey Nikolaevich Osipov
Cited by: 1
References: 27

Abstract

New gold (I) complexes with bulky fluorinated N-heterocyclic carbene ligands were synthesized and fully characterized. Their catalytic activity was tested in model reactions such as intramolecular hydroamination of 2-(phenylethynyl)aniline, alkyne hydration and hydrohydrazination of henylacetylene. In all studied cases new complexes demonstrated from good to excellent catalytic activities under standard conditions.

Fields of Study & Subjects

Catalytic Alkyne Reactions N-Heterocyclic Carbenes in Organic and Inorganic Chemistry Catalytic Cross-Coupling Reactions

Publication details

Journal / source
Mendeleev Communications
Publisher
OOO Zhurnal "Mendeleevskie Soobshcheniya"
Volume
36
Issue
2
Pages
197–199
Publication date
1 January 2026
Language
RU