Synthesis and transformations of mesoionic imidazol-3-ium-4-olate carbaldehydes

Mendeleev Communications 2026

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Authors: Konstantin Evgen'evich Shepelenko, Maxim Aleksandrovich Shevchenko, Yurii N. Tkachenko, Mikhail Evgenievich Minyaev, Чернышев Виктор Михайлович
DOI: 10.71267/mencom.7920
Cited by: 0
References: 19

Abstract

A simple synthesis of previously inaccessible 1,3-diaryl-5-formyl-1H-imidazol-3-ium-4-olates has been developed via the Vilsmeier-Haack formylation of 4-hydroxy-1,3-diarylimidazolium chlorides. The potential applicability of the obtained 5-formyl-functionalized imidazolium olates to serve as building blocks for preparing diverse multifunctional imidazole compounds has been demonstrated through the reactions with N- and C-nucleophiles.

Fields of Study & Subjects

Synthesis and Reactions of Organic Compounds N-Heterocyclic Carbenes in Organic and Inorganic Chemistry Ionic liquids properties and applications

Publication details

Journal / source
Mendeleev Communications
Volume
36
Issue
2
Pages
177–179
Publication date
1 January 2026
Language
RU