Thermally activated (NHC)NiCp2 precatalysts for the cross-coupling of amines with aryl chlorides

Mendeleev Communications 2026 Open access

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Authors: Oleg Vladimirovich Khazipov, Anastasia S. Pyatachenko, Daria V. Chernysheva, Чернышев Виктор Михайлович
DOI: 10.71267/mencom.7937
Cited by: 0
References: 28

Abstract

Readily accessible (NHC)NiCp2 complexes were identified as efficient thermally activated precatalysts for the C-N cross-coupling reaction between unactivated aryl chlorides and anilines or secondary aliphatic amines. The optimized catalytic system enables the selective coupling of sterically hindered partners and tolerates fluoride substituents in the aromatic rings.

Fields of Study & Subjects

Catalytic Cross-Coupling Reactions N-Heterocyclic Carbenes in Organic and Inorganic Chemistry Catalytic C–H Functionalization Methods

Publication details

Journal / source
Mendeleev Communications
Volume
36
Issue
3
Pages
276–278
Publication date
1 January 2026
Language
RU