Electron temperature relations and the direct N, O, Ne, S and Ar abundances of 49959 star-forming galaxies in DESI Data Release 2

We present the largest direct-method abundance catalogue of galaxies to date, containing measurements of 49959 star-forming galaxies at z < 0.96 from DESI Data Release 2. By directly measuring electron temperatures across multiple ionisation zones, we provide constraints on a number of electron temperature relations. Using the temperature measurements, we derive reliable abundances for N, O, Ne, S and Ar and measure the evolution of abundances and abundance ratios of as a function of metallicity and other galaxy properties. Our measurements include direct oxygen abundances for 49507 galaxies, leading to the discovery of the two most metal-poor galaxies in the nearby Universe, with oxygen abundances of 12+log(O/H) = $\rm 12+\log(O/H) = 6.77_{-0.03}^{+0.03}~\rm dex $ (1.2\% $\rm Z_{\odot}$) and $\rm 12+\log(O/H) = 6.81_{-0.04}^{+0.04}~\rm dex$ (1.3\% $\rm Z_{\odot}$). We identify a rare outlier population of 24 galaxies with high N/O ratios at low metallicity, reminiscent of galaxy abundances observed in the early Universe. We find the Ne/O ratio is constant at low metallicity but increases gradually at $\rm 12+log(O/H) > 8.105\pm0.004$ dex. We show that the S/O and Ar/O abundance ratios are strongly correlated, consistent with the expected additional Type Ia enrichment channel for S and Ar. In this work we present an initial survey of the key properties of the sample, with this dataset serving as a foundation for extensive future work on galaxy abundances at low redshift.