Third-Order Geometric-Volume Conservation in Cahn--Hilliard Models

Degenerate Cahn-Hilliard phase-field models provide a robust approximation of surface-diffusion-driven interface motion without explicit front tracking. In computations, however, the geometric volume enclosed by the interface -- the region where the order parameter $ϕ$ is positive -- may drift at finite interface thickness, producing artificial shrinkage or growth even when the sharp-interface limit conserves volume. We revisit and extend the improved-conservation framework of Zhou et al., where one replaces classical mass conservation by the exact conservation of a designed monotone mapping $Q(ϕ)$ that more accurately approximates a step function. Building on this framework, we (i) carry out the matched-asymptotic analysis in the unscaled physical time formulation, (ii) derive a simplified representation of the first-order inner correction to the interface profile, and (iii) identify an integral-moment cancellation condition that controls the leading geometric-volume defect. This mechanism becomes a practical design rule: we select regularization kernels within parameterized families -- including exponential and Pade-type -- to reach effective higher-order behavior and satisfy the cancellation condition at moderate parameter values. As a result, the proposed kernels achieve formal third-order accuracy in geometric-volume conservation with respect to interface thickness. Finally, we describe an unconditional energy-dissipative numerical discretization that exactly preserves the discrete conserved quantity. Numerical benchmarks on multi-scale droplet coarsening and shape relaxation demonstrate that the moment-balanced kernels virtually eliminate artificial drift and prevent premature extinction of small droplets.